Patent-Based Prospective Life Cycle Assessment and Eco-Design of Lithium–Sulfur Batteries

Abstract

Lithium–sulfur batteries (LSBs) are a promising emerging technology due to their high energy density, low-cost materials, and safety. However, their environmental sustainability is not yet well understood. This study conducted a prospective life cycle assessment (LCA) on two patented LSB models, using data from patents as the inventory: one with a standard sulfur cathode and another with a graphene–sulfur composite (GSC). The assessment is conducted for a functional unit of 1 Wh of produced electricity, adopting a cradle-to-gate system boundary and a prospective time horizon set to 2035. The LSB GSC model battery showed significantly better performance in terms of climate change and fossil depletion, with a 42% lower impact, mainly due to a reduction in the lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) content from 1205 mg Wh−1 to 250 mg Wh−1. However, the GSC model also had significant drawbacks, showing a 93% higher metal depletion and 49% higher water depletion than the standard sulfur battery. Building on an established patent-based prospective LCA approach, this work applies patent-derived quantitative inventories and patent-informed eco-design analysis to support environmentally informed design decisions for emerging LSB technologies prior to large-scale commercialization.