Preparation of Supercapacitors on Flexible Substrates with Electrodeposited PEDOT/Graphene Composites
Lehtimäki, Suvi; Suominen, Milla; Damlin, Pia; Tuukkanen, Sampo; Kvarnström, Carita; Lupo, Donald (2015-10-14)
Lehtimäki, Suvi
Suominen, Milla
Damlin, Pia
Tuukkanen, Sampo
Kvarnström, Carita
Lupo, Donald
14.10.2015
Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi:tty-201605033910
https://urn.fi/URN:NBN:fi:tty-201605033910
Kuvaus
Peer reviewed
Tiivistelmä
Composite films consisting of poly(3,4-ethylenedioxythiophene) (PEDOT) and graphene oxide (GO) were electrochemically polymerized by electrooxidation of EDOT in ionic liquid (BMIMBF4) onto flexible electrode substrates. Two polymerization approaches were compared, and the cyclic voltammetry (CV) method was found to be superior to potentiostatic polymerization for the growth of PEDOT/GO films. After deposition, incorporated GO was reduced to rGO by a rapid electrochemical method of repetitive cathodic potential cycling, without using any reducing reagents. The films were characterized in 3-electrode configuration in BMIMBF4. Symmetric supercapacitors with aqueous electrolyte were assembled from the composite films and characterized through cyclic voltammetry and galvanostatic discharge tests. It was shown that PEDOT/rGO composites have better capacitive properties than pure PEDOT or the unreduced composite film. The cycling stability of the supercapacitors was also tested, and the results indicate that the specific capacitance still retains well over 90% of the initial value after 2000 consecutive charging/discharging cycles. The supercapacitors were demonstrated as energy storages in a room light energy harvester with a printed organic solar cell and printed electrochromic display. The results are promising for the development of energy-autonomous, low-power, and disposable electronics.
Kokoelmat
- TUNICRIS-julkaisut [19034]